Wet hydrogen sulfide h2s cracking inspectioneering. Hydrogen sulfide h 2 s is a colorless, flammable, and extremely hazardous gas with a strong rotten egg odor. Bastien and amiot, mechanism of the effect of ionized. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods.
However, stress corrosion cracking scc of dss equipment has been experienced in different pulp mills. Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfidecontaining solutions has been useful for material selection in many. The results support film rupture for albrass and sulfide stress corrosion cracking assisted with pitting corrosion for cu10ni at slip steps as the operating mechanisms. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. In some cases crack initiation has been associated with the formation of a brittle film at the surface of the material, which could have lower ductility due to a different metal. Corrosion testing lab services,hydrogen induced disbonding laboratory,stress corrosion testing lab as per astm,nace standards. Dunlop, thus, concluded that the eac mechanism was a form of scc, i. Low alloy steels, stress corrosion cracking, sulfide stress cracking tagged with. Ian sutton, in plant design and operations second edition, 2017.
The susceptibility of p110 downhole tubular steel to. Hydrogen sulfide is particularly dangerous to equipment when moisture is present. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Dunlop named this type of eac sulfide corrosion stress cracking. Bala srinivasan,helmholtzzentrum geesthacht, germanyand v. The results indicate that flow control valve body failed due to combination of hydrogeninduced corrosion cracking and sulfide stress corrosion cracking. To check its resistance to scc and ssc, several tests were performed. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to. Cracking threshold stress is very high, and is assumed to be about 100kgmm 2. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. The steels sscc susceptibility was determined by constant load tensile according to nace tm0177 standard. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength alloys and steels when it comes in contact with humid hydrogen sulfide as well as sulfidic atmospheres.
Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfide containing solutions has been useful for material selection in many. Part one covers the mechanisms of scc and hydrogen embrittlement, while the focus of part two is on methods of testing for scc in metals. The cracking is affected by environmental conditions such as hydrogen sulfide partial pressure and temperature. Notch tensile slow strain rate testing ntssrt method is used to evaluate the threshold stress intensity values kisscc. Sulphide stress cracking ssc is the biggest concern 9. Which alloy is for sulfide stress and stress corrosion.
It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. The stress can be externally applied or it can be an internal residual stress. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion. This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sridhar ramamurthy and andrej atrens stress corrosion. Stresscorrosion cracking experiments can be categorized as. In order to quantitatively evaluate the cracking susceptibility on this steel in the wet h2s environment, the prefatigue crack mwol specimen stress corrosion cracking tests in three h2s concentrations were performed under the.
Tests on statically loaded smooth samples tests on statically loaded precracked samples tests using slowly straining samples more detailed information on these tests can be found in chapter 17, evaluation of stress corrosion cracking, in this book, and in ref 1. A study on the mechanism of stress corrosion cracking of. Some researchers consider sulfidestress cracking a type of stresscorrosion. Stress corrosion cracking scc is the type of failure mechanism caused by a combination of environmental, material and stress conditions fig. The stress corrosion cracking behaviour of uns n08031 in. Stress corrosion cracking of welded 2205 duplex stainless.
Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h. The environment causing stresscorrosion cracking scc at the top of a distillation tower in a crude oil refinery was reproduced in the laboratory.
Assessment of the sulfide stress corrosion cracking. Which alloy is best to resist sulfide stress cracking and stress corrosion cracking. Amine cracking typically occurs on the surface and the cracks are usually radially. Sulfide stress corrosion cracking sscc in crude oil field environment containing hydrogen sulfide h 2 s has been recognized as a material degradation and damage mechanism. At present there are two main theories for sulfide corrosion cracking, namely hydrogen embrittlement mechanism and stress corrosion cracking mechanism. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. Standard material requirements sulfide stress cracking. The reason for this is the complexity of the damage mechanism which is dependent on the particular material and damaging medium. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3. Some researchers consider sulfidestress cracking a type of stress corrosion.
Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulfide stress cracking ssc also known as sour gas cracking sour gas. Stress corrosion cracking scc is the simultaneous action of a tensile stress and an aggressive environment on an alloy system to produce a brittle fracture in a normally ductile material at stress levels far below engineering design limits. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. A study of the sulfide stress corrosion cracking in. Sulfide stress corrosion cracking and hydrogen induced. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Although there are several kinds of cracking damage that can occur in metals, delayed brittle fracture of metals resulting from the combined action of corrosion in an aqueous sulfide environment and tensile stresses failure may occur at stresses far below the yield stress is the phenomenon known as ssc.
Amine cracking is often intertwined with wet hydrogen sulfide h 2 s and carbonate cracking, as amines, carbonates and wet sulfides often exist together in amine treating systems. This paper analyzed the hsla pipeline steels stress corrosion behavior and mechanism which tested in the saturated solution of h2s. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Laboratory testing of metals for resistance to sulfide stress. For instance, a failsafe limit line for sus 304 is 80c for hydrogen sulfide partial pressure of 1. Hydrogen sulfide stress corrosion cracking of high. Is sulfide stress cracking an anodic or a cathodic process. The susceptibility of a high strength low alloy nanostructured steel to sulfide stress corrosion cracking sscc resistance is assessed. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. These comparisons illustrate the need to design environmental cracking tests which reflect both corrosion mechanism factors and application requirements.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Duplex stainless steel dss grades are used in pulp mills for their superior properties and resistance to general corrosion. As a form of hydrogen stress cracking, ssc is a cracking mechanism in. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. The use of dss has been restricted in some cases because of stress corrosion cracking scc, which can initiate and grow in either the ferrite or austenite phase depending on the environment. Hence, in many situations, this test has been used as a screening test.
In recognition of the variation with temperature and with different materials this phenomenon is here called environmental cracking ec. Many changes have been made with austenitic stainless steels. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Sulfide stress cracking of pipelinecase history onepetro. Sulfide stress cracking how is sulfide stress cracking. Element sulfide stress cracking ssc testing according the nace tm0177 iso.
In addition, a general comparison is made of the testing requirements for the sulfide stress cracking system and for anodic stress corrosion cracking systems involving hydrogen sulfide. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. Sulfide stress cracking an overview sciencedirect topics. The sulfide ions up to 500 ppm has no effect on the stress corrosion cracking of the annealed albrass in 3. In late 2003, it became nace mr0175 iso 15156, petroleum and natural gas industries materials for use in h 2. Standard material requirements metals for sulfide stress. Which alloy is for sulfide stress and stress corrosion cracking.
Sulfide stress cracking is the cracking of a metal under the combined action. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. Laboratory data and field experience have demonstrated that extremely low concentration of h 2 s may be sufficient to lead to sscc failure of susceptible materials. Sulfide stress cracking oil and gas pipelines wiley online library. Alloys which are commercially available and those which have modified metallurgical structures and.
It has a great tendency to the problem of environmental cracking under the service condition of lpg containing wet h2s surpassing the lowest allowance for steels. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. The results indicate that flow control valve body failed due to combination of hydrogen induced corrosion cracking hicc and sulfide stress corrosion cracking sscc. Sulfide stress cracking nace mr01752002, mr0175iso. Corrosionpedia what is sulfide stress cracking ssc. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Hydrogen sulfide stress corrosion cracking in materials. Sulfide stress crackingnace mr01752002, mr0175iso 15156 650 te c h n i c a l the details nace mr0175, sulfide stress corrosion cracking resistant metallic materials for oil field equipment is widely used throughout the world. Sulfide stress corrosion cracking of steels corrosion.
Stress corrosion cracking of stainless steels in hydrogen. Laboratory testing of metals for resistance to sulfide. Corrigendum sulfide stress cracking of nickelcontaining. Effect of sulfide ions on the stress corrosion behaviour of. Summary sulfide stress cracking ssc is just one of several forms of. A probable mechanism for iron dissolution in aqueous solutions containing h 2 s based on the formation of mackinawite film, as proposed by sun et al. Iso 151563 will set new restrictions on uns s174000 174ph october 22, 2014 by mariano. Hydrogen sulfide stress corrosion cracking of stainless steels. The variation of the name is due to the lack of agreement in the mechanism of failure. It was an acidified hydrogen sulfide solution with a. H 2 s damage can lead to rapid and extensive damage to metals, including uniform corrosion, pitting, and stepwise cracking. Standard test method laboratory testing of metals for. Sulfide stress cracking ssc vs hydrogen induced cracking.
Hydrogen sulfide stress corrosion cracking in materials for. Hydrogen sulphide stress corrosion cracking in materials for. Amine cracking is a form of stress corrosion cracking, which is related to alkaline and carbonate stress corrosion cracking. An industry value that has been developed is nace mr01. According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217 wc9. The topics include laser surface melting to repair stress corrosion cracking in weld metal, pulsed laser surface treatment of multilayer goldnickelcopper coatings to improve the corrosion resistance of components in electronics, liquid impingement erosion resistance, modifying the surface of steel to resist slurry erosion in power plants, and laser surface remelting to improve the erosion. Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing. Tests include stress corrosion cracking scc,hydrogen induced cracking test hic, sulfide stress corrosion cracking sscc, intergranular corrosion igc and sulfide stress corrosion cracking sscc at elevated temperature,india,maharashtra,mumbai,bombay,asia. Damage due to hydrogen embrittlement and stress corrosion.
Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels, martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, duplex stainless steels, nickelcopper alloys, and nickelbase alloys. Pdf sulfide stress corrosion cracking and hydrogen. The susceptibility of dss grades to scc can be mainly attributed to the various heating processes involved during the manufacturing of industrial equipments. Corrosion testing lab,stress corrosion,materials,hydrogen. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. The poorly known mechanism of h 2 s corrosion makes it difficult to quantify the kinetics of iron sulfide scale formation. The experience of task group t1f9 members with different types of stress corrosion cracking specimens for standardization is summarized and presented here. Sulfide stress cracking of highstrength steels is a problem in handling sour hydrogen sulfide containing crude oil or natural gas. The latter observation is contrary to the predictions of a mechanism of hydrogen embrittlement based on molecular hydrogen pressure but it is shown to be consistent with those of an internal adsorption mechanism. According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217wc9 cast crmo steel.